Coal liquefaction is an industrial process in which coal as raw material, through chemical reactions, is converted into liquid hydrocarbon mixture, which, under further processing, becomes desired liquid fuels or chemical feedstock. Therefore, the main purpose of coal liquefaction lies in production of either synthetic oil as a partial
Pyrite addition to a coal liquefaction process (22, 26) is controlled (118) in inverse proportion to the calcium content of the feed coal to maximize the F. ( C.) liquid yield per unit weight of pyrite added (110). The pyrite addition is controlled in this manner so as to minimize the amount of pyrite used and ...
We have launched ISKG for indirect coal liquefaction process, its oriented applications are of great significance in optimizing HAZOP, strengthening industrial safety and popularizing safety prevention awareness. Section 2 is the related work, which mainly reviews HAZOP and KG. Section 3 is the method, we elaborate the development process of ...
The effective utilization of the coal liquefaction residue (CLR), which contains about 80% organic matter, is of great significancefor improving the oil yield of the direct liquefaction process ...
reported a twostage liquefaction process with Tanito Harum coal (Indonesian subbituminous coal) under the hydrogen pressure of 15 MPa using 10 wt% Fe10 wt% Ni catalyst supported on carbon nanoparticles. Under the optimal conditions of the two stage liquefaction: 380 °C for 15 min in the first stage and 450 °C for 105 min in the second ...
Coal liquefaction residue (CLR) is usually categorized as hazardous waste, which is inevitably generated during the coalliquefaction process. Studies show that CLR has a high calorific value and can be used to decrease coal consumption during the cofiring process. In this regard, field tests were carried out to study the emission and ...
Coal liquefaction technology is one of the most impactive technology to realize clean and efficient utilization of coal. In the process of indirect coal liquefaction to produce synthetic oil, a inevitable byproduct refer as indirect coal liquefaction residue (ICLR) that accounts for about 30 % of raw coal will be produced [3], [4].
CCLP Chevron Coal Liquefaction Process CCS Carbon capture and storage CO Carbon monoxide CO 2 Carbon dioxide CPI OPECConsumer Price Index CTL Coaltoliquids DCL Direct coal liquefaction DME Dimethyl ether DOD Department of Defense DOE Department of Energy EDS Exxon Donor Solvent ...
Indirect liquefaction requires an intermediate gasification of the solid coal to form a synthesis gas, which is then converted to the liquid product. This process results in the complete dismantling of the coal structure. direct liquefaction, coal is exposed directly to hydrogen at high temperatures (450C) and high pressures (kPa ...
Since the late 1970s, coal liquefaction processes have been developed into integrated twostage processes, in which coal is liquefied in the presence of hydrogen in the first stage and the products are upgraded in the second stage.
[1] The indirect route is composed of 2 steps: First, coal is gasified with steam and oxygen to produce a synthesis gas (syngas), which is then cleaned to rid of dust, tar, and acid gases.
4 Liquefaction. Coal liquefaction is the process of making a liquid fuel from coal. The fundamental difference between coal, a solid, and liquid fuels is that the liquid fuels have a higher hydrogen:carbon ratio. Liquid fuels have lower ash contents and are easier to upgrade (, to remove unwanted impurities such as nitrogen and sulfur). ...
Direct coal liquefaction involves contacting coal directly with a catalyst at elevated temperatures and pressures with added hydrogen (H 2 ), in the presence of a solvent to form a raw liquid product which is further refined into product liquid fuels.
Progress on US ERDA's coal liquefaction research and development programs is reported. This included operation of the SRC pilot plant to produce 400 tons of specification solventrefined coal, process development efforts related to the Synthoil process, site selection and engineering for the Hcoal process pilot plant, and renovation of the Cresap test facility (for testing components).
article{osti_, title = {Catalyst withdrawal and addition in a coal liquefaction process}, author = {Simone, A A and Ogren, D F}, abstractNote = {The catalyst is withdrawn from a coal hydroliquefaction reactor while it is maintained on stream by withdrawing a portion of the catalyst, in a separate stream, dispersed in product from the liquefaction zone, with such withdrawn stream being ...
Figure (A) Schematic representation of elution zones of different chemical families representative of a coalderived middle distillate; (B) SFCFID chromatogram of a coalderived middle distillate using the pyridine bonded phase showing the huge resolution of phenols from hydrocarbons.
Coal liquefaction is the conversion of coal to a cleanburning, lowsulfercontent fuel which can augment gasoline and boiler fuels. Direct liquefaction processes are currently in the research and development stage and are expected to yield a high percentage of boiler fuels for industry and utilities. Indirect liquefaction processes are ...
A typical liquefaction process, NEDOL process, applied 728 K, 17 MPa, a metal catalyst, and a hydrogen supplier solvent for the coal depolymerization. A significant problem of coal liquefaction is that the conditions are too severe, so the cost of the heat energy and plant device is too high to be commercialized.
Even though the process is currently not in use, it has contributed immensely to the development of catalytic coal liquefaction technology. The process involves the catalytic conversion of coal (slurried with heavy oil) in the presence of hydrogen and an iron oxide catalyst, at 450°C500°C and 200690 bars (197681 atm, or 2069 MPa).
One of several direct liquefaction processes currently under advanced stages of development is the SolventRefined CoalI (SRCI) process. A major SRC1 product option is a low sulfur, low ash solid (SRC) which could be used as an electric utility boiler fuel much in the same manner that pulverized coal is currently fired in this type of combustion equipment.
Process. The Exxon donor solvent process is a noncatalytic processing of solventslurried coal in a highpressure liquefaction reactor. Coal is cleaned, crushed and fed to the slurry dryer, where water is removed. The dry crushed coal is slurried with the hydrogen donor recycle solvent. The coal slurry is treated with hydrogen and heated in a ...
Therefore, while direct coal liquefaction (DCL) takes coal directly into a liquid phase, indirect coal liquefaction (ICL) consists of two major steps: (a) gasification to produce a synthesis gas (syngas); and (b) conversion of the carbon monoxide (CO) and hydrogen (H 2) in the syngas to a range of hydrocarbon fuels/products such as gasoline, die...
The primary liquid emissions from coal conversion processes are heavily contaminated by ammonia, sulphides and other inorganics, as well as by phenolic and other organic compounds. The solid wastes are derived from coal ash, spent catalyst, and solid sludges. Previous chapter Next chapter 1. Introduction 62 2. Gasification 65
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